MSDS loctite3106

Revision Number: 006.2

Issue date: 02/05/2010

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: Product type:

3106 UV Curing General Purpose Adhesive

Ultraviolet adhesive

IDH number: 168331 Item number: 23698 Region: United States Contact information: Telephone: 860.571.5100

Emergency telephone: 860.571.5100 Internet: www.henkelna.com

Company address: Henkel Corporation One Henkel Way

Rocky Hill, Connecticut 06067

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *2 Color: Transparent, Slightly Hazy FLAMMABILITY: 2 Odor: Mild PHYSICAL HAZARD: 1 Personal Protection: See MSDS Section 8

WARNING:

COMBUSTIBLE LIQUID AND VAPOR.

HARMFUL IF SWALLOWED, ABSORBED THROUGH SKIN OR INHALED. DO NOT SPRAY. DO NOT HEAT.

MAY CAUSE ALLERGIC SKIN REACTION.

CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.

Skin, Inhalation, Eyes

Relevant routes of exposure:

Potential Health Effects

Inhalation: Skin contact: Eye contact: Ingestion:

Existing conditions aggravated by exposure:

See Section 11 for additional toxicological information.

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Eye, skin, and respiratory disorders.

Modified acrylamide is harmful if inhaled. Causes respiratory tract irritation. Vapors and mists will irritate nose and throat and possibly eyes. Headache. Nausea. DO NOT heat or spray as this increases the inhalation hazard.

Modified acrylamide may be absorbed through skin in harmful amounts. Toxic. May cause allergic skin reaction. Causes skin irritation. Contact with eyes will cause irritation.

Modified acrylamide is harmful if swallowed. Toxic.

IDH number: 168331

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Product name: 3106 UV Curing General Purpose Adhesive

3. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous components

Urethane Polymer Acrylate monomer Modified acrylamide Photoinitiator

Substituted silane

Silica, amorphous, fumed, crystal-free Photoinitiator

2-Hydroxyethyl acrylate

CAS NUMBER Proprietary Proprietary 2680-03-7 24650-42-8 Proprietary 112945-52-5 Proprietary 818-61-1

% 30 - 60 30 - 60 10 - 30 1 - 5 1 - 5 1 - 5 1 - 5 0.1 - 1

4. FIRST AID MEASURES

Inhalation:

Skin contact:

Eye contact:

Ingestion:

Do not induce vomiting. Never give anything by mouth to an unconscious person. Keep individual calm. Get medical attention.

Flush with copious amounts of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Get medical attention. Immediately wash skin thoroughly with soap and water. Remove contaminated clothing and footwear. Wash clothing before reuse. If symptoms develop and persist, get medical attention.

Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention.

5. FIRE FIGHTING MEASURES

Flash point:

Autoignition temperature:

Flammable/Explosive limits - lower:

Flammable/Explosive limits - upper:

Extinguishing media:

Special firefighting procedures:

Unusual fire or explosion hazards:

Hazardous combustion products:

Oxides of carbon. Oxides of nitrogen. Oxides of silicon. Irritating organic vapours. Toxic fumes. Isocyanates. Hydrogen cyanide. Amines. Collect

contaminated fire extinguishing water separately. This must not be discharged into drains.

Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers.

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Water may be unsuitable as an extinguishing media, but may be helpful in keeping adjacent containers cool.

Water spray (fog), foam, dry chemical or carbon dioxide. Not available Not available Not available

77.8 °C (172.04 °F) Pensky Martens closed cup

6. ACCIDENTAL RELEASE MEASURES

Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected

personnel.

Environmental precautions: Remove all sources of ignition. Do not allow product to enter sewer or

waterways.

IDH number: 168331

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Product name: 3106 UV Curing General Purpose Adhesive

Clean-up methods:

Ensure adequate ventilation. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. Refer to Section 8 \"Exposure Controls / Personal Protection\" prior to clean up.

7. HANDLING AND STORAGE

Handling:

Use only with adequate ventilation. Prevent contact with eyes, skin and

clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not taste or swallow. DO NOT heat or spray. Use only in area provided with appropriate exhaust ventilation. Refer to Section 8.

For safe storage, store at or below 26 °C (78.8 °F)

Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

Storage:

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.

Hazardous components Urethane Polymer Acrylate monomer Modified acrylamide

ACGIH TLV None None None

OSHA PEL

AIHA WEEL

OTHER

None None None None None None 0.1 mg/m3 TWA

(Skin)

None None 0.025 ppm TWA

(Skin)

None None None None None None 20 MPPCF TWA 0.8 mg/m3 TWA

None None Photoinitiator None Substituted silane None

10 mg/m3 TWA Inhalable dust.

Silica, amorphous, fumed, crystal-free

3 mg/m3 TWA Respirable fraction.

Photoinitiator None 2-Hydroxyethyl acrylate None

Engineering controls:

Respiratory protection:

None None None None None None Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits.

Use NIOSH approved respirator if there is potential to exceed exposure limit(s). If this material is handled at elevated temperatures or under mist

forming conditions, without engineering controls, a NIOSH approved respirator must be used.

Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Neoprene gloves.

Eye/face protection:

Skin protection:

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Color: Odor:

Odor threshold: pH:

Vapor pressure: Boiling point/range: Melting point/ range:

Liquid

Transparent, Slightly Hazy Mild

Not available Not applicable

< 5 mm hg (20 °C (68°F)) > 200 °F (> 93.3 °C) Not available

IDH number: 168331

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Product name: 3106 UV Curing General Purpose Adhesive

Specific gravity: 1.078 Vapor density: > 1 Flash point: 77.8 °C (172.04 °F) Pensky Martens closed cup Flammable/Explosive limits - lower: Not available Flammable/Explosive limits - upper: Not available

Autoignition temperature: Not available Evaporation rate: Not available

Solubility in water: Slight Partition coefficient (n-octanol/water): Not available VOC content: 2.16 %; 23.28 g/l (process) 1.05 %; 11.32 g/l (potential) 3.21 %; 34.60 g/l (total) (ASTM D03)

10. STABILITY AND REACTIVITY

Stability:

Hazardous reactions:

Hazardous decomposition products:

Incompatible materials:

Conditions to avoid:

Keep away from heat, spark and flame. Avoid temperatures above 26°C (80°F). Store away from incompatible materials. Direct sunlight. Ultraviolet radiation. Freezing conditions.

Strong oxidizing agents. Strong acids. Strong bases. Amines. Alkalis. Peroxides. Free radical initiators.

Oxides of carbon. Oxides of nitrogen. Oxides of silicon. Irritating organic vapours. Isocyanates. Hydrogen cyanide. Amines. May occur.

Stable under normal conditions of storage and use.

11. TOXICOLOGICAL INFORMATION

Acute dermal product toxicity:

Acute inhalation product toxicity: Modified acrylamide LC50 (rat) 1 h > 776 ppm (vapor)

OSHA Carcinogen

Hazardous components NTP Carcinogen IARC Carcinogen

(Specifically Regulated) Urethane Polymer Acrylate monomer Modified acrylamide Photoinitiator

Substituted silane

Silica, amorphous, fumed, crystal-free Photoinitiator

2-Hydroxyethyl acrylate Hazardous components

Urethane Polymer Acrylate monomer Modified acrylamide Photoinitiator

Substituted silane

Silica, amorphous, fumed, crystal-free Photoinitiator

2-Hydroxyethyl acrylate

No No No No No No No No

Health Effects/Target Organs

No Records Irritant, Allergen Irritant, Eyes, Mutagen, Kidney, Less weight gain and food intake. No Target Organs Irritant, Allergen Nuisance dust No Records Allergen, Central nervous system, Heart, Irritant, Kidney, Liver, Lung, Some

evidence of carcinogenicity, Spleen

No No No No No No No No

No No No No No No No No

Modified acrylamide LD50 (rabbit) 518 mg/kg

Acute oral product toxicity: Modified acrylamide LD50 (rat) 316 mg/kg

IDH number: 168331

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Product name: 3106 UV Curing General Purpose Adhesive

12. ECOLOGICAL INFORMATION

Ecological information:

Not available

13. DISPOSAL CONSIDERATIONS

Information provided is for unused product only.

Recommended method of disposal:

Hazardous waste number:

Not a RCRA hazardous waste.

Dispose of according to Federal, State and local governmental regulations.

14. TRANSPORT INFORMATION

The shipping classification in this section are for bulk packaging only. Shipping classification may be different for non-bulk packaging as exceptions may apply. Refer to shipping documents for package specific transportation classification.

U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Combustible liquid, n.o.s. (Modified Acrylamide) Hazard class or division: Combustible Liquid Identification number: NA 1993 Packing group: III

International Air Transportation (ICAO/IATA) Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (2,2-Dimethoxy-1,2-diphenylethan-1-one, Isobornyl acrylate) Hazard class or division: 9 Identification number: UN 3082 Packing group: III

Water Transportation (IMO/IMDG) Proper shipping name:

Hazard class or division: Identification number: Packing group: Marine pollutant:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (2,2-Dimethoxy-1,2-diphenylethan-1-one, Isobornyl acrylate) 9

UN 3082 III

2,2-Dimethoxy-1,2-diphenylethan-1-one, Isobornyl acrylate

15. REGULATORY INFORMATION

United States Regulatory Information

TSCA 8 (b) Inventory Status:

TSCA 12(b) Export Notification:

CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313:

California Proposition 65:

Canada Regulatory Information

CEPA DSL/NDSL Status:

No California Proposition 65 listed chemicals are known to be present. None above reporting de minimus

Immediate Health, Delayed Health, Fire None above reporting de minimus

All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.

None above reporting de minimus

WHMIS hazard class:

Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. B.3, D.1.B, D.2.B

IDH number: 168331

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Product name: 3106 UV Curing General Purpose Adhesive

16. OTHER INFORMATION

This material safety data sheet contains changes from the previous version in sections: 1,5,8,10,12,14

Prepared by: Tricia Voghell, Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any

production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits.

IDH number: 168331

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Product name: 3106 UV Curing General Purpose Adhesive